Synthesis and 1,3-dipolar cycloadditions of a new enantiopure cyclic nitrone

被引：25

作者：

Alibés, R

Blanco, P

de March, P

Figueredo, M ^{[1
]}

Font, J

Alvarez-Larena, A

Piniella, JF

机构：

[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

[2] Univ Autonoma Barcelona, Unit Cristallog, E-08193 Barcelona, Spain

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 03期

关键词：

enantiopure cyclic nitrone; dipolar cycloaddition; facial selectivity;

D O I：

10.1016/S0040-4039(02)02587-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new enantiopure cyclic nitrone has been efficiently synthesized from a D-glyceraldehyde derivative. It's 1,3-dipolar cycloaddition to different classes of dipolarophiles show complete antifacial selectivity, furnishing highly functionalized enantiopure bicyclic isoxazolidines. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：523 / 525

页数：3

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