Amorphous Molecular Organic Solids for Gas Adsorption

被引：141

作者：

Tian, Jian ^{[1
]}

Thallapally, Praveen K. ^{[2
]}

Dalgarno, Scott J. ^{[3
]}

McGrail, Peter B. ^{[2
]}

Atwood, Jerry L. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Pacific NW Natl Lab, Richland, WA 99352 USA

[3] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 30期

关键词：

adsorption; amorphous materials; molecular organic solids; solid-state structures; INTRINSIC MICROPOROSITY PIMS; CARBON-DIOXIDE; COORDINATION POLYMER; RETICULAR SYNTHESIS; STORAGE; HYDROGEN; METHANE; NORIA; DESIGN; CO2;

D O I：

10.1002/anie.200900479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fixing the hole: Molecular organic compounds with large accessible internal cavities display gas-storage ability in the amorphous solid state. This finding suggests for the first time that longrange molecular order is not a prerequisite for organic molecules to be engineered as porous materials. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5492 / 5495

页数：4

共 41 条

[1]

Ananchenko G. S., 2008, ANGEW CHEM, V120, P5698

[2] A channel-free soft-walled capsular calixarene solid for gas adsorption [J].