Unprecedented host-induced intramolecular charge-transfer complex formation

被引:111
作者
Lee, JW
Kim, K
Choi, S
Ko, YH
Sakamoto, S
Yamaguchi, K
Kim, K
机构
[1] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Div Mol & Life Sci, Pohang 790784, South Korea
[3] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 2638522, Japan
关键词
D O I
10.1039/b208280b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time, host-induced intramolecular charge-transfer complex formation in a guest containing both an electron donor and an electron acceptor is demonstrated in the cucurbit[8]uril cavity, leading to unusual back-folding of the guest molecule.
引用
收藏
页码:2692 / 2693
页数:2
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