A triptycene-based polymer of intrinsic microposity that displays enhanced surface area and hydrogen adsorption

被引：266

作者：

Ghanem, Bader S.

Msayib, Kadhum J.

McKeown, Neil B. ^{[1
]}

Harris, Kenneth D. M.

Pan, Zhigang

Budd, Peter M.

Butler, Anna

Selbie, James

Book, David

Walton, Allan

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England

[3] Univ Birmingham, Dept Met & Mat, Sch Engn, Birmingham B15 2TT, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b614214a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel triptycene-based polymer of intrinsic microporosity (Trip-PIM) displays enhanced surface area (1065 m(2) g(-1)) and reversibly adsorbs 1.65% hydrogen by mass at 1 bar/77 K and 2.71% at 10 bar/77 K.

引用

页码：67 / 69

页数：3

共 30 条

[1] Hydrogen adsorption on a single-walled carbon nanotube material:: a comparative study of three different adsorption techniques
Ansón, A
Benham, M
Jagiello, J
Callejas, MA
Benito, AM
Maser, WK
Züttel, A
Sudan, P
Martínez, MT
[J]. NANOTECHNOLOGY, 2004, 15 (11) : 1503 - 1508
[2] Free volume and intrinsic microporosity in polymers
Budd, PM
McKeown, NB
Fritsch, D
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (20) : 1977 - 1986
[3] Gas separation membranes from polymers of intrinsic microporosity
Budd, PM
Msayib, KJ
Tattershall, CE
Ghanem, BS
Reynolds, KJ
McKeown, NB
Fritsch, D
[J]. JOURNAL OF MEMBRANE SCIENCE, 2005, 251 (1-2) : 263 - 269
[4] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials
Budd, PM
Ghanem, BS
Makhseed, S
McKeown, NB
Msayib, KJ
Tattershall, CE
[J]. CHEMICAL COMMUNICATIONS, 2004, (02) : 230 - 231
[5] Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity
Budd, PM
Elabas, ES
Ghanem, BS
Makhseed, S
McKeown, NB
Msayib, KJ
Tattershall, CE
Wang, D
[J]. ADVANCED MATERIALS, 2004, 16 (05) : 456 - +
[6] A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support
Budd, PM
Ghanem, B
Msayib, K
McKeown, NB
Tattershall, C
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) : 2721 - 2726
[7] High H2 adsorption in a microporous metal-organic framework with open metal sites
Chen, BL
Ockwig, NW
Millward, AR
Contreras, DS
Yaghi, OM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) : 4745 - 4749
[8] Synthesis of a novel poly(iptycene) ladder polymer
Chen, ZH
Amara, JP
Thomas, SW
Swager, TM
[J]. MACROMOLECULES, 2006, 39 (09) : 3202 - 3209
[9] Porous, crystalline, covalent organic frameworks
Côté, AP
Benin, AI
Ockwig, NW
O'Keeffe, M
Matzger, AJ
Yaghi, OM
[J]. SCIENCE, 2005, 310 (5751) : 1166 - 1170
[10] High surface area nanoporous polymers for reversible hydrogen storage
Germain, Jonathan
Hradil, Jiri
Frechet, Jean M. J.
Svec, Frantisek
[J]. CHEMISTRY OF MATERIALS, 2006, 18 (18) : 4430 - 4435

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