An improved procedure for the palladium-catalyzed oxidative carbonylation of β-amino alcohols to oxazolidin-2-ones

被引：88

作者：

Gabriele, B ^{[1
]}

Mancuso, R

Salerno, G

Costa, M

机构：

[1] Univ Calabria, Dipartimento Sci Farmaceut, I-87036 Cosenza, Italy

[2] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

[3] Univ Calabria, Dipartimento Chim, I-87036 Cosenza, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 02期

关键词：

D O I：

10.1021/jo026532a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient oxidative cyclocarbonylation of beta-amino alcohols and 2-aminophenol to oxazolidin-2-ones has been achieved by using PdI2 in conjunction with KI as the catalytic system in DME under relatively mild conditions (100 degreesC and 20 atm of a 4:1 mixture of CO and air).

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收藏

页码：601 / 604

页数：4

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