Chemical and electronic surface structure of 20%-efficient Cu(In,Ga)Se2 thin film solar cell absorbers

被引:56
作者
Baer, M. [1 ,2 ]
Repins, I. [3 ]
Contreras, M. A. [3 ]
Weinhardt, L. [4 ]
Noufi, R. [3 ]
Heske, C. [1 ]
机构
[1] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA
[2] Helmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany
[3] Natl Renewable Energy Lab, Golden, CO 80401 USA
[4] Univ Wurzburg, D-97074 Wurzburg, Germany
关键词
conduction bands; copper compounds; energy gap; Fermi level; indium compounds; photoelectron spectra; semiconductor thin films; solar cells; surface structure; ternary semiconductors; thin film devices; BAND ALIGNMENT; HETEROJUNCTION; CHALCOPYRITE; EFFICIENCY; INTERFACE; CUINSE2;
D O I
10.1063/1.3194153
中图分类号
O59 [应用物理学];
学科分类号
摘要
The chemical and electronic surface structure of 20%-efficient Cu(In,Ga)Se-2 thin film solar cell absorbers was investigated as a function of deposition process termination (i.e., ending the growth process in absence of either Ga or In). In addition to the expected In (Ga) enrichment, direct and inverse photoemission reveal a decreased Cu surface content and a larger surface band gap for the "In-terminated" absorber.
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页数:3
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