Study of hydrogen adsorption properties on MCM-41 mesoporous materials modified with nickel

被引:27
作者
Carraro, P. [1 ,3 ]
Elias, V. [3 ,5 ]
Garcia Blanco, A. A. [4 ]
Sapag, K. [4 ]
Eimer, G. [3 ,5 ]
Oliva, M. [1 ,2 ]
机构
[1] Univ Nacl Cordoba, CONICET, IFEG, RA-5000 Cordoba, Argentina
[2] Univ Nacl Cordoba, FAMAF, RA-5000 Cordoba, Argentina
[3] Univ Tecnol Nacl, CITeQ, Fac Reg Cordoba, Cordoba, Argentina
[4] Univ Nacl San Luis, CONICET, INFAP, Lab Solidos Porosos, San Luis, Argentina
[5] Consejo Nacl Invest Cient & Tecn, RA-1033 Buenos Aires, DF, Argentina
关键词
MCM-41; Nickel; Hydrogen storage;
D O I
10.1016/j.ijhydene.2013.12.038
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MCM-41 samples were modified with different Ni loadings by wet impregnation method and characterized by XRD, ICP, EPMA-EDS, N-2 adsorption-desorption and hydrogen adsorption at 77 K at high and low pressure conditions. The hydrogen adsorption studies for the MCM-41 host and the impregnated samples showed that small amounts of Ni ions in MCM-41 improved the hydrogen storage capacity by spillover effect. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:8749 / 8753
页数:5
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