A comparative study of various microporous materials to store hydrogen by physical adsorption

被引：33

作者：

Garcia Blanco, A. A. ^{[1
]}

Vallone, A. F. ^{[1
]}

Gil, A. ^{[2
]}

Sapag, K. ^{[1
]}

机构：

[1] Univ Nacl San Luis, CONICET, INFAP, Lab Solidos Porosos, RA-5700 San Luis, Argentina

[2] Univ Publ Navarra, Dept Quim Aplicada, E-31006 Pamplona, Spain

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2012年 / 37卷 / 19期

关键词：

Hydrogen storage; Microporous materials; Hydrogen adsorption; Textural properties; METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; MIL-53; METHANE; ENHANCEMENT;

D O I：

10.1016/j.ijhydene.2012.01.166

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, a comparative study of various porous materials to be used as an alternative to store hydrogen by a physical adsorption process was presented. There was selected, among those commercially available, a set of the most recognized microporous materials namely: zeolites, activated carbons, carbon nanotubes and metal-organic frameworks. These samples were exhaustively characterized by nitrogen adsorption-desorption and studied in hydrogen adsorption at sub atmospheric and high pressure conditions. Discussions of the correlation between surface area and micropore volumes were performed through the adjustment of specific models, analyses on adsorbate adsorbent interaction and differences in the adsorbed volumes of hydrogen by each material. Finally were discussed the properties that should be improved in the materials to make viable the hydrogen storage by adsorption. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：14870 / 14880

页数：11

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