Structural impact of infinite water chains on the self-assembly of an inorganic-metal-organic architecture

被引:70
作者
Reger, DL [1 ]
Semeniuc, RF
Pettinari, C
Luna-Giles, F
Smith, MD
机构
[1] Univ S Carolina, Dept Chem & Biochem, 631 Sumter St, Columbia, SC 29208 USA
[2] Univ Camerino, Dept Chem, I-62032 Camerino, MC, Italy
[3] Univ Extremadura, Dept Quim Inorgan, E-06071 Badajoz, Spain
关键词
D O I
10.1021/cg050669n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of {p-C6H4[CH2OCH2C(pz)(3)](2)[Ru(p-cymene)(2)}Cl-4 center dot 14H(2)O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer with chloride anions by hydrogen bonds. This layer acts as a "host" supporting the non-self-assembled metal-organic "guests".
引用
收藏
页码:1068 / 1070
页数:3
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