Anions as templates in coordination and supramolecular chemistry

被引:253
作者
Gimeno, Nelida [1 ]
Vilar, Ramon [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
关键词
anion; template; macrocycles; cages; catenanes; rotaxanes;
D O I
10.1016/j.ccr.2006.05.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review aims to highlight the most important recent advances in the area of anion-templated syntheses in supramolecular and coordination chemistry. We published a comprehensive review on this area in 2003 and hence examples prior to this date will only be discussed when essential for clarity of presentation. The current review has been divided into three main sections: (a) anion-templated synthesis of systems with well-defined molecular weights; this includes macrocycles and cages, interlocked species (such as catenanes and rotaxanes), helical assemblies and other selected examples. (b) Anions as templates in polymeric systems; this includes metal-organic frameworks, molecularly imprinted polymers and other selected examples, such as liquid crystalline materials. (c) Anion templates in dynamic combinatorial libraries. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3161 / 3189
页数:29
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