Bis[bis(triphenylphosphoranylidene)-ammonium] pentachlorofluoroosmate(IV) hydrate, [(C6H5)(3)P=N=P(C6H5)(3)](2)-[OsFCl5].H2O

被引：4

作者：

Bruhn, C

Preetz, W

机构：

[1] Inst. für Anorganische Chemie, Universität Kiel, D-24098 Kiel

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S010827019601061X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, (C36H30NP2)(2-) [OsCl5F].H2O, has been determined by single-crystal X-ray diffraction at 208 K. The octahedral [OsCl5F](2-) complex anions are completely ordered in an A(2)B-type lattice. The monoclinic unit cell contains four formula units, each with a solvent water molecule linked to the F atom by a hydrogen bond [O ... F 2.737 (8) Angstrom]. The Os-F bond [1.960(4) Angstrom] is weakened by trans influence and, correspondingly, the Os-Cl1 bond [2.307 (2) Angstrom] trans to Os-F is strengthened compared with the average Os-Cl bond length along the Cl-Os-Cl axes of 2.339 Angstrom.

引用

收藏

页码：63 / 66

页数：4

相关论文

共 17 条

[1] ELECTRONIC WAVE-FUNCTIONS AND SOLUTION NUCLEAR MAGNETIC-RESONANCE PARAMETERS OF SOME MIXED FLUOROCHLORO-OSMATES(IV) [J].

ALYOUBI, AO ;

GREENSLADE, DJ ;

FORSTER, MJ ;

PREETZ, W .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (01) :381-385

[2] DIPYRIDINIOMETHANE DIIODIDE [J].

BRUDGAM, I ;

HARTL, H .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :866-868

[3] DIPYRIDINIOMETHANE TRANS-DICHLOROTETRAFLUOROOSMATE(IV) HYDRATE, TRANS-[(C5H5N)(2)CH2][OSF4CL2].H2O [J].

BRUHN, C ;

PREETZ, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :865-867

[4] FAC-DIPYRIDINIOMETHANE AND MER-DIPYRIDINIOMETHANE TRICHLOROTRIFLUOROOSMATE(IV), FAC-[(C5H5N)(2)CH2][OSCL3F3] AND MER-[(C5H5N)(2)CH2][OSCL3F3] [J].

BRUHN, C ;

PREETZ, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :1112-1116

[5] DIPYRIDINIOMETHANE CHLOROPENTAFLUOROOSMATE(IV), [(C5H5N)(2)CH2][OSF5CL] [J].

BRUHN, C ;

PREETZ, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :1687-1690

[6] DIPYRIDINIOMETHANE CIS-DICHLOROTETRAFLUOROOSMATE(IV) [J].

BRUHN, C ;

PREETZ, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :1555-1557

[7] CRYSTAL-STRUCTURES, VIBRATIONAL-SPECTRA, AND NORMAL-COORDINATE ANALYSES OF THE STEREOISOMERIC TRIFLUOROTRICHLOROPLATINATES(IV),FAC-[(C5H5N)(2)CH2][PTF3CL3]CENTER-DOT-0.5(CH3)(2)CO AND MER-[(C5H5N)(2)CH2][PTF3CL3] [J].

BRUHN, C ;

DREWS, HH ;

MEYNHARDT, B ;

PREETZ, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (03) :373-380

[8] Dipyiridiniomethane cis- and trans-difluorotetrachloroosmate(IV), cis- and trans-[(C5H5N)(2)CH2][OsCl4F2] [J].

Bruhn, C ;

Preetz, W .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 (pt 2) :321-325

[9]

*ENR NON, 1994, CAD 4 PC VERS 1 5C

[10]

FAIR CK, 1990, MOLEN INTERACTIVE IN