One-step fabrication of ZnWO4 hollow spheres by nanoparticle aggregation and ripening in alcohol solution

被引：29

作者：

Huang, Jianhua ^{[1
]}

Gao, Lian ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2006年 / 89卷 / 12期

关键词：

D O I：

10.1111/j.1551-2916.2006.01318.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A one-step method has been developed to synthesize ZnWO4 spheres with a hollow-core diameter of 450 nm and an outer spherical diameter of 1.2 mu m. Experimental investigation reveals that the ZnWO4 spheres are formed through nanoparticle aggregation and ripening. Furthermore, introduction of appropriate water quantity to the reaction system is a key to obtain hollow-core ZnWO4. The as-obtained ZnWO4 hollow spheres exhibit a blue emission in the range of 350-550 nm, centered around 460 nm when excited at 254 nm.

引用

收藏

页码：3877 / 3880

页数：4

相关论文

共 27 条

[1] A versatile method for the production of monodisperse spherical particles and hollow particles:: Templating from binary core-shell structures [J].

Arnal, PM ;

Schüth, F ;

Kleitz, F .

CHEMICAL COMMUNICATIONS, 2006, (11) :1203-1205

[2] Conversion of colloidal ZnO-WO3 heteroaggregates into strongly blue luminescing ZnWO4 xerogels and films [J].

Bonanni, M ;

Spanhel, L ;

Lerch, M ;

Fuglein, E ;

Muller, G ;

Jermann, F .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :304-310

[3] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].

Caruso, F ;

Caruso, RA ;

Möhwald, H .

SCIENCE, 1998, 282 (5391) :1111-1114

[4] Fabrication of nanocrystalline ZnWO4 with different morphologies and sizes via hydrothermal route [J].

Chen, SJ ;

Zhou, JH ;

Chen, XT ;

Li, J ;

Li, LH ;

Hong, JM ;

Xue, ZL ;

You, XZ .

CHEMICAL PHYSICS LETTERS, 2003, 375 (1-2) :185-190

[5] Recent advances in the liquid-phase syntheses of inorganic nanoparticles [J].

Cushing, BL ;

Kolesnichenko, VL ;

O'Connor, CJ .

CHEMICAL REVIEWS, 2004, 104 (09) :3893-3946

[6] SCINTILLATION PROPERTIES OF ZNWO4 [J].

GRASSMANN, H ;

MOSER, HG ;

LORENZ, E .

JOURNAL OF LUMINESCENCE, 1985, 33 (01) :109-113

[7] Multistep coating of thick titania layers on monodisperse silica nanospheres [J].

Guo, XC ;

Dong, P .

LANGMUIR, 1999, 15 (17) :5535-5540

[8] Nanocages derived from shell cross-linked micelle templates [J].

Huang, HY ;

Remsen, EE ;

Kowalewski, T ;

Wooley, KL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (15) :3805-3806

[9] Preparation and characterization of titania-coated polystyrene spheres and hollow titania shells [J].

Imhof, A .

LANGMUIR, 2001, 17 (12) :3579-3585

[10] Selective hydrogenation by Pd nanoparticles embedded in polyelectrolyte multilayers [J].

Kidambi, S ;

Dai, JH ;

Li, J ;

Bruening, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (09) :2658-2659