Synthesis and Structure of an Unprecedented Linear Pentanuclear Bismuth(III) Zwitterionic Thiolate Complex

被引：6

作者：

Chen, Jin-Xiang ^{[1
,2
]}

Tang, Xiao-Yan ^{[1
]}

Ren, Zhi-Gang ^{[1
]}

Zhang, Yong ^{[1
]}

Lang, Jian-Ping ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China

[2] So Med Univ, Sch Pharmaceut Sci, Guangzhou 510515, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 01期

关键词：

Bismuth; Zwitterions; S ligands; Structure elucidation; MOLECULAR-STRUCTURE; CHEMISTRY; SILVER; RINGS;

D O I：

10.1002/ejic.200800969

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A unique pentanuclear bismuth(III) zwitterionic thiolate complex, [Bi-5(Tab)(18)](PF6)(7)(NO3)(8)]center dot 6MeCN [1; Tab = 4-(trimethylammonio)benzenethiolato], was obtained from the reaction of Bi(NO3)(3) with TabHPF(6) in a 1:4 molar ratio in MeCN/MeOH in the presence of Et3N and structurally characterized, Single-crystal X-ray diffraction revealed that 1 consists of an unprecedented linear [Bi-5(Tab)(18)](15+) cation, and both [PF6](-) and [NO3](-) anions in the crystal cooperatively work as anionic templates to form interesting anionic honeycomb-like cavities for encapsulating the [Bi-5(Tab)(18)](15+) cations. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：38 / 41

页数：4

共 33 条

[1] Molecular structure and theoretical studies of (PPh4)2[Bi10Cu10(SPh)24] [J].

Ahlrichs, Reinhart ;

Eichhoefer, Andreas ;

Fenske, Dieter ;

May, Klaus ;

Sommer, Heino .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) :8254-8257

[2]

[Anonymous], 1997, SHELXL 97 SHELXS 97

[3] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A HOMOLEPTIC BISMUTH ARENETHIOLATE [J].

ATWOOD, DA ;

COWLEY, AH ;

HERNANDEZ, RD ;

JONES, RA ;

RAND, LL ;

BOTT, SG ;

ATWOOD, JL .

INORGANIC CHEMISTRY, 1993, 32 (13) :2972-2974

[4] Ammoniumthiolatobismuth halides:: a new thiolate bonding environment for BiIII as an alternative to metathesis and chelation [J].

Briand, GG ;

Burford, N ;

Cameron, TS .

CHEMICAL COMMUNICATIONS, 1997, (24) :2365-2366

[5] Defining and controlling the aminoethanethiolate chemistry of bismuth(III): Synthesis and comprehensive characterization of the homologous thiolatobismuth series [J].

Briand, GG ;

Burford, N ;

Cameron, TS ;

Kwiatkowski, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (44) :11374-11379

[6] ARSENITES AND ANTIMONITES .2. VIBRATIONAL, NUCLEAR-QUADRUPOLE RESONANCE, AND MASS-SPECTRAL PROPERTIES OF ARSENIC(III) AND ANTIMONY(III) ESTERS AND THIOESTERS [J].

BRILL, TB ;

CAMPBELL, NC .

INORGANIC CHEMISTRY, 1973, 12 (08) :1884-1888

[7] Synthesis and molecular structure of the dihydrobis(thioxotriazolinyl)borato complexes of zinc(II), bismuth(III), and nickel(II).: M•••H-B interaction studied by ab initio calculations [J].

Cammi, R ;

Lanfranchi, M ;

Marchiò, L ;

Mora, C ;

Paiola, C ;

Pellinghelli, MA .

INORGANIC CHEMISTRY, 2003, 42 (05) :1769-1778

[8] The preparation and structural characterisation of thiolato anions of bismuth(III) [J].

Charmant, JPH ;

Jahan, AHMM ;

Norman, NC ;

Orpen, AG .

INORGANICA CHIMICA ACTA, 2005, 358 (05) :1358-1364

[9] Coordination polymers formed by Bi(SC6F5)3 with multidentate polypyridyl ligands [J].

Charmant, JPH ;

Jahan, AHMM ;

Norman, NC ;

Orpen, AG ;

Podesta, TJ .

CRYSTENGCOMM, 2004, 6 :29-33

[10] Toward rational construction of gold, gold-silver, and gold-mercury string complexes:: Syntheses, structures, and properties of [Au(Tab)2]2L2 (L = I and PF6), {[(Tab)2M][Au(CN)2]}2 (M = Au and Ag), and {[Hg(Tab) 2][Au(CN)2]2} [Tab=4-(trimethylammonio)benzenethiolate] [J].

Chen, Jin-Xiang ;

Zhang, Wen-Hua ;

Tang, Xiao-Yan ;

Ren, Zhi-Gang ;

Li, Hong-Xi ;

Zhang, Yong ;

Lang, Jian-Ping .

INORGANIC CHEMISTRY, 2006, 45 (19) :7671-7680

← 1 2 3 4 →