Synthesis and Structure of an Unprecedented Linear Pentanuclear Bismuth(III) Zwitterionic Thiolate Complex

被引：6

作者：

Chen, Jin-Xiang ^{[1
,2
]}

Tang, Xiao-Yan ^{[1
]}

Ren, Zhi-Gang ^{[1
]}

Zhang, Yong ^{[1
]}

Lang, Jian-Ping ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China

[2] So Med Univ, Sch Pharmaceut Sci, Guangzhou 510515, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 01期

关键词：

Bismuth; Zwitterions; S ligands; Structure elucidation; MOLECULAR-STRUCTURE; CHEMISTRY; SILVER; RINGS;

D O I：

10.1002/ejic.200800969

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A unique pentanuclear bismuth(III) zwitterionic thiolate complex, [Bi-5(Tab)(18)](PF6)(7)(NO3)(8)]center dot 6MeCN [1; Tab = 4-(trimethylammonio)benzenethiolato], was obtained from the reaction of Bi(NO3)(3) with TabHPF(6) in a 1:4 molar ratio in MeCN/MeOH in the presence of Et3N and structurally characterized, Single-crystal X-ray diffraction revealed that 1 consists of an unprecedented linear [Bi-5(Tab)(18)](15+) cation, and both [PF6](-) and [NO3](-) anions in the crystal cooperatively work as anionic templates to form interesting anionic honeycomb-like cavities for encapsulating the [Bi-5(Tab)(18)](15+) cations. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：38 / 41

页数：4

共 33 条

[11] Assembly of a new family of mercury(II) zwitterionic thiolate complexes from a preformed compound [Hg(Tab)2](PF6)2 [Tab=4-(trimethylammonio)benzenethiolate] [J].

Chen, JX ;

Zhang, WH ;

Tang, XY ;

Ren, ZG ;

Zhang, Y ;

Lang, JP .

INORGANIC CHEMISTRY, 2006, 45 (06) :2568-2580

[12] Solid-state reactions of AgAc with TabHPF6 at room temperature -: Isolation and structural characterisation of an unusual octadecanuclear silver thiolate cluster [Ag9(Tab)8(MeCN)8]2(PF6)18•4MeCN [Tab=4-(trimethylammonio)benzenethiolate] [J].

Chen, JX ;

Xu, QF ;

Xu, Y ;

Zhang, Y ;

Chen, ZN ;

Lang, JP .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (21) :4247-4252

[13] Isolation, structure and spectroscopic characterization of silver complexes of the zwitterionic thiolate Tab:: [Ag3(Tab)2](PF6, {[Ag3(Tab)4]PF6)3•2DMF}n, and [Ag14(μ6-S)(Tab)12(PPh3)8] (PF6)12(Tab=4-(trimethylammonio)benzenethiolate) [J].

Chen, JX ;

Xu, QF ;

Zhang, Y ;

Chen, ZN ;

Lang, JP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (06) :1071-1077

[14] Polynuclear bismuth selenolates:: rings en route to clusters [J].

DeGroot, MW ;

Corrigan, JF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (08) :1235-1236

[15] SYNTHETIC ANALOGS OF ACTIVE-SITES OF IRON-SULFUR PROTEINS .6. SPECTRAL AND REDOX CHARACTERISTICS OF TETRANUCLEAR CLUSTERS [FE4S4(SR)4]2- [J].

DEPAMPHILIS, BV ;

AVERILL, BA ;

HERSKOVITZ, T ;

QUE, L ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (13) :4159-4167

[16] BISMUTH(III) THIOLATES - SYNTHESES AND THE STRUCTURES OF A NEUTRAL THIOLATE AND A THIOLATO ANION [J].

FARRUGIA, LJ ;

LAWLOR, FJ ;

NORMAN, NC .

POLYHEDRON, 1995, 14 (02) :311-314

[17] Bismuth(III) thioether chemistry:: the synthesis and structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n•nH2O, a highly unusual network involving Bi4Cl4 rings and bridging dithioether ligands [J].

Genge, ARJ ;

Levason, W ;

Reid, G .

CHEMICAL COMMUNICATIONS, 1998, (19) :2159-2160

[18] Unprecedented polycrystal structure of a new cadmium thiolate containing an unusually highly charged [ClCd8{SCH(CH2CH2)2N(H)Me}16]15+ core [J].

Gonzàlez-Duarte, P ;

Clegg, W ;

Casals, I ;

Sola, J ;

Rius, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (06) :1260-1266

[19]

Jadwiger A., 1982, BIOCHEM BIOPH RES CO, V108, P919

[20]

KLAPOTKE T, 1987, Z NATURFORSCH B, V42, P940

← 1 2 3 4 →