Chemical stability of glass seal interfaces in intermediate temperature solid oxide fuel cells

被引:80
作者
Yang, ZG [1 ]
Xie, GG [1 ]
Meinhardt, KD [1 ]
Weil, KS [1 ]
Stevenson, JW [1 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
关键词
ferritic stainless steels; interconnect; sealing glass; solid oxide fuel cell;
D O I
10.1361/10599490419298
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In intermediate temperature planar solid oxide fuel cell (SOFC) stacks, the interconnect, which is typically made from cost-effective, oxidation-resistant, high-temperature alloys, is typically sealed to the ceramic positive electrode-electrolyte-negative electrode (PEN) by a sealing glass. To maintain the structural stability and minimize the degradation of stack performance, the sealing glass has to be chemically compatible with the PEN and alloy interconnects. In the present study, the chemical compatibility of a barium-calcium-aluminosilicate (BCAS) based glass-ceramic (specifically developed as a sealant in SOFC stacks) with a number of selected oxidation resistant high temperature alloys (and the yttria-stabilized zirconia electrolyte) was evaluated. This paper reports the results of that study, with a particular focus on Crofer22 APU, a new ferritic stainless steel that was developed specifically for SOFC interconnect applications.
引用
收藏
页码:327 / 334
页数:8
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