Biaryl synthesis from two different aryl halides with tri(2-furyl)germane

被引:65
作者
Nakamura, T [1 ]
Kinoshita, H [1 ]
Shinokubo, H [1 ]
Oshima, K [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan
关键词
D O I
10.1021/ol026613t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is acheived. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides.
引用
收藏
页码:3165 / 3167
页数:3
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