A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions

被引：278

作者：

Tao, J

Zhang, Y

Tong, ML

Chen, XM ^{[1
]}

Yuen, T

Lin, CL

Huang, XY

Li, J

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Xiamen Univ, Sch Chem & Chem Engn, Xiamen 361005, Peoples R China

[3] Temple Univ, Dept Phys, Philadelphia, PA 19122 USA

[4] Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b203301a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu-2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper( II)oxygen interactions.

引用

页码：1342 / 1343

页数：2

共 29 条

[1]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[2]

2-Z

[3] Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits [J].