Cathodic Deposition of Polypyrrole Enabling the One-Step Assembly of Metal-Polymer Hybrid Electrodes

被引：60

作者：

Jung, Yongju ^{[1
]}

Singh, Nikhilendra ^{[1
]}

Choi, Kyoung-Shin ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 44期

关键词：

cathodic deposition; conducting materials; hybrid electrodes; polymers; tin; LITHIUM-ION BATTERIES; IRREVERSIBLE CAPACITY; HYDROGEN EVOLUTION; COMPOSITE; TIN; FILMS; MECHANISMS; NANOWIRES; ANODE;

D O I：

10.1002/anie.200903596

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deposit account: The generation of oxidizing agents in situ allows the cathodic deposition of polypyrrole (ppy) by oxidative polymerization. Conducting polymers are synthesized with new nanoscale morphologies (e.g., nanospheres creating a three-dimensional porous network, see picture). Metal-conducting polymer hybrid electrodes are assembled by a onestep synthesis. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：8331 / 8334

页数：4

相关论文

共 33 条

[1] Polymers in sensor applications [J].

Adhikari, B ;

Majumdar, S .

PROGRESS IN POLYMER SCIENCE, 2004, 29 (07) :699-766

[2] Nanostructured materials for advanced energy conversion and storage devices [J].

Aricò, AS ;

Bruce, P ;

Scrosati, B ;

Tarascon, JM ;

Van Schalkwijk, W .

NATURE MATERIALS, 2005, 4 (05) :366-377

[3] Anomalous, high-voltage irreversible capacity in tin electrodes for lithium batteries [J].

Beattie, SD ;

Hatchard, T ;

Bonakdarpour, A ;

Hewitt, KC ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :A701-A705

[4]

Bruce P.G., 2008, Angew. Chem, V120, P2972

[5] Low band gap polymers for organic photovoltaics [J].

Bundgaard, Eva ;

Krebs, Frederik C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (11) :954-985

[6] Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries [J].

Fan, J ;

Wang, T ;

Yu, CZ ;

Tu, B ;

Jiang, ZY ;

Zhao, DY .

ADVANCED MATERIALS, 2004, 16 (16) :1432-+

[7] FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS [J].

GUSTAFSSON, G ;

CAO, Y ;

TREACY, GM ;

KLAVETTER, F ;

COLANERI, N ;

HEEGER, AJ .

NATURE, 1992, 357 (6378) :477-479

[8] High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries [J].

Hassoun, Jusef ;

Panero, Stefania ;

Simon, Patrice ;

Taberna, Pierre Louis ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (12) :1632-+

[9]

Holleman A.F., 2001, Inorganic Chemistry, P661

[10] Irreversible capacity of electrodeposited Sn thin film anode [J].

Inaba, M ;

Uno, T ;

Tasaka, A .

JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :473-477

← 1 2 3 4 →