Ancillary ligand control of reactivity. Protonation at hydride vs cyanide in trans-[FeH(CN)(R(2)PCH(2)CH(2)PR(2))(2)] (R=Et, Ph, p-tolyl) and X-ray crystal structure determination of trans-[FeH(CNH)(R(2)PCH(2)CH(2)PR(2))2]BF4 (R=p-tolyl)

被引：24

作者：

Amrhein, PI ^{[1
]}

Drouin, SD ^{[1
]}

Forde, CE ^{[1
]}

Lough, AJ ^{[1
]}

Morris, RH ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 14期

关键词：

D O I：

10.1039/cc9960001665

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ancillary ligands in trans-[FeH(CN)L(2)] control whether protonation occurs at hydride to produce a dihydrogen complex or at cyanide to produce a hydrogen isocyanide complex.

引用

页码：1665 / 1666

页数：2

共 24 条

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