Synthesis, Characterization, Luminescence, and Non-linear Optical Properties of Oxadiazole- and Truxene-Containing Platinum(II) Alkynyl Complexes with Donor-Acceptor Functionalities

被引：72

作者：

Chan, Carmen Ka Man ^{[1
,2
]}

Tao, Chi-Hang ^{[1
,2
]}

Tam, Hoi-Lam ^{[3
,4
]}

Zhu, Nianyong ^{[1
,2
]}

Yam, Vivian Wing-Wah ^{[1
,2
]}

Cheah, Kok-Wai ^{[3
,4
]}

机构：

[1] Univ Hong Kong, Ctr Carbon Rich Mol & Nanoscale Met Based Mat Res, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Hong Kong, Hong Kong, Peoples R China

[4] Hong Kong Baptist Univ, Dept Phys, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 07期

关键词：

EXCITATION CROSS-SECTIONS; 2-PHOTON ABSORPTION; STRUCTURAL-CHARACTERIZATION; MLCT TRANSITION; MOLECULAR FLUOROPHORES; ACETYLIDE COMPLEXES; ORGANIC-MOLECULE; BUILDING-BLOCKS; RESONANCE RAMAN; DATA STORAGE;

D O I：

10.1021/ic8017979

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of luminescent platinum(II) alkynyl complexes containing 2,5-diphenyl-1,3,4-oxadiazole (oxa-2,5) and 10, 15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) as the cores and different electron donors at the periphery has been synthesized and characterized. These complexes showed long-lived emissions in both solution and in the solid state at room temperature and have been found to exhibit two-photon absorption (2PA) and two-photon induced luminescence. Their 2PA cross-sections (sigma(2)) have also been determined.

引用

收藏

页码：2855 / 2864

页数：10

相关论文

共 75 条

[21] NEW ORGANOMETALLIC SOLIDS [J].

GREEN, MLH ;

QIN, J ;

OHARE, D ;

BUNTING, HE ;

THOMPSON, ME ;

MARDER, SR ;

CHATAKONDU, K .

PURE AND APPLIED CHEMISTRY, 1989, 61 (05) :817-822

[22] SYNTHESIS AND STRUCTURE OF (CIS)-[1-FERROCENYL-2-(4-NITROPHENYL)ETHYLENE], AN ORGANOTRANSITION METAL COMPOUND WITH A LARGE 2ND-ORDER OPTICAL NONLINEARITY [J].

GREEN, MLH ;

MARDER, SR ;

THOMPSON, ME ;

BANDY, JA ;

BLOOR, D ;

KOLINSKY, PV ;

JONES, RJ .

NATURE, 1987, 330 (6146) :360-362

[23] 3-DIMENSIONAL CONFOCAL FLUORESCENCE IMAGING UNDER ULTRASHORT-PULSE ILLUMINATION [J].

GU, M ;

TANNOUS, T ;

SHEPPARD, CJR .

OPTICS COMMUNICATIONS, 1995, 117 (5-6) :406-412

[24] OPTICAL LIMITING EFFECT IN A 2-PHOTON ABSORPTION DYE-DOPED SOLID-MATRIX [J].

HE, GS ;

BHAWALKAR, JD ;

ZHAO, CF ;

PRASAD, PN .

APPLIED PHYSICS LETTERS, 1995, 67 (17) :2433-2435

[25] Two-photon pumped cavity lasing in novel dye doped bulk matrix rods [J].

He, GS ;

Zhao, CF ;

Bhawalkar, JD ;

Prasad, PN .

APPLIED PHYSICS LETTERS, 1995, 67 (25) :3703-3705

[26] 2-PHOTON ABSORPTION BASED OPTICAL LIMITING AND STABILIZATION IN ORGANIC MOLECULE-DOPED SOLID MATERIALS [J].

HE, GS ;

GVISHI, R ;

PRASAD, PN ;

REINHARDT, BA .

OPTICS COMMUNICATIONS, 1995, 117 (1-2) :133-136

[27] Phosphorescent platinum(II) complexes derived from multifunctional chromophores: Synthesis, structures, photophysics, and electroluminescence [J].

He, Ze ;

Wong, Wai-Yeung ;

Yu, Xiaoming ;

Kwok, Hoi-Sing ;

Lin, Zhenyang .

INORGANIC CHEMISTRY, 2006, 45 (26) :10922-10937

[28] Synthesis and characterization of new fluorescent two-photon absorption chromophores [J].

Huang, PH ;

Shen, JY ;

Pu, SC ;

Wen, YS ;

Lin, JT ;

Chou, PT ;

Yeh, MCP .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (09) :850-857

[29] Synthesis, characterization, and photophysical properties of some heterodimetallic bisporphyrins of ytterbium and transition metals -: Enhancement and lifetime extension of Yb3+ emission by transition-metal porphyrin sensitization [J].

Jiang, Feng-Lei ;

Wong, Wai-Kwok ;

Zhu, Xun-Jin ;

Zhou, Gui-Jiang ;

Wong, Wai-Yeung ;

Wu, Po-Lam ;

Tam, Hoi-Lam ;

Cheah, Kok-Wai ;

Ye, Cheng ;

Liu, Yi .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (21) :3365-3374

[30] Delocalization in platinum-alkynyl systems:: A metal-bridged organic mixed-valence compound [J].

Jones, SC ;

Coropceanu, V ;

Barlow, S ;

Kinnibrugh, T ;

Timofeeva, T ;

Brédas, JL ;

Marder, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (38) :11782-11783

← 1 2 3 4 5 6 7 8 →