Synthesis, Characterization, Luminescence, and Non-linear Optical Properties of Oxadiazole- and Truxene-Containing Platinum(II) Alkynyl Complexes with Donor-Acceptor Functionalities

被引：72

作者：

Chan, Carmen Ka Man ^{[1
,2
]}

Tao, Chi-Hang ^{[1
,2
]}

Tam, Hoi-Lam ^{[3
,4
]}

Zhu, Nianyong ^{[1
,2
]}

Yam, Vivian Wing-Wah ^{[1
,2
]}

Cheah, Kok-Wai ^{[3
,4
]}

机构：

[1] Univ Hong Kong, Ctr Carbon Rich Mol & Nanoscale Met Based Mat Res, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Hong Kong, Hong Kong, Peoples R China

[4] Hong Kong Baptist Univ, Dept Phys, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 07期

关键词：

EXCITATION CROSS-SECTIONS; 2-PHOTON ABSORPTION; STRUCTURAL-CHARACTERIZATION; MLCT TRANSITION; MOLECULAR FLUOROPHORES; ACETYLIDE COMPLEXES; ORGANIC-MOLECULE; BUILDING-BLOCKS; RESONANCE RAMAN; DATA STORAGE;

D O I：

10.1021/ic8017979

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of luminescent platinum(II) alkynyl complexes containing 2,5-diphenyl-1,3,4-oxadiazole (oxa-2,5) and 10, 15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) as the cores and different electron donors at the periphery has been synthesized and characterized. These complexes showed long-lived emissions in both solution and in the solid state at room temperature and have been found to exhibit two-photon absorption (2PA) and two-photon induced luminescence. Their 2PA cross-sections (sigma(2)) have also been determined.

引用

页码：2855 / 2864

页数：10

共 75 条

[41] 2-PHOTON PUMPED UP-CONVERTED LASING IN DYE-DOPED POLYMER WAVE-GUIDES [J].

MUKHERJEE, A .

APPLIED PHYSICS LETTERS, 1993, 62 (26) :3423-3425

[42] Processing of X-ray diffraction data collected in oscillation mode [J].

Otwinowski, Z ;

Minor, W .

MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326

[43] 3-DIMENSIONAL OPTICAL STORAGE MEMORY [J].

PARTHENOPOULOS, DA ;

RENTZEPIS, PM .

SCIENCE, 1989, 245 (4920) :843-845

[44] Star-shaped polycyclic aromatics based on oligothiophene-functionalized truxene: Synthesis, properties, and facile emissive wavelength tuning [J].

Pei, J ;

Wang, JL ;

Cao, XY ;

Zhou, XH ;

Zhang, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) :9944-9945

[45] Nonlinear optical properties of transition metal acetylides and their derivatives [J].

Powell, CE ;

Humphrey, MG .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (7-8) :725-756

[46] Platinum acetylide two-photon chromophores [J].

Rogers, Joy E. ;

Slagle, Jonathan E. ;

Krein, Douglas M. ;

Burke, Aaron R. ;

Hall, Benjamin C. ;

Fratini, Albert ;

McLean, Daniel G. ;

Fleitz, Paul A. ;

Cooper, Thomas M. ;

Drobizhev, Mikhail ;

Makarov, Nikolay S. ;

Rebane, Aleksander ;

Kim, Kye-Young ;

Farley, Richard ;

Schanze, Kirk S. .

INORGANIC CHEMISTRY, 2007, 46 (16) :6483-6494

[47] SITE-SELECTIVE SPECTROSCOPY OF LUMINESCENT SQUARE-PLANAR PLATINUM(II) COMPLEXES [J].

SACKSTEDER, L ;

BARALT, E ;

DEGRAFF, BA ;

LUKEHART, CM ;

DEMAS, JN .

INORGANIC CHEMISTRY, 1991, 30 (11) :2468-2476

[48] Synthesis and properties of polyacetylenes having pendant carbazole groups [J].

Sanda, F ;

Kawaguchi, T ;

Masuda, T ;

Kobayashi, N .

MACROMOLECULES, 2003, 36 (07) :2224-2229

[49] Supramolecular array of imizazolylethynyl-zinc-porphyrin [J].

Satake, Akiharu ;

Shoji, Osami ;

Kobuke, Yoshiaki .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (1-3) :635-644

[50] ALKYNYL CHLORIDE EXCHANGE BETWEEN TRANS-PLATINUM(II) AND TRANS-PALLADIUM(II) CHLORIDES AND ALKYNYLSTANNANES - CRYSTAL-STRUCTURE OF TRANS-[BIS(1-PROPYNYL)-BIS(TRIETHYLPHOSPHINE)PLATINUM(II)] [J].

SEBALD, A ;

STADER, C ;

WRACKMEYER, B ;

BENSCH, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (1-2) :233-242

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