Intervalence charge transfer (IVCT) in trinuclear and tetranuclear complexes of iron, ruthenium, and osmium

被引：295

作者：

D'Alessandro, Deanna M. ^{[1
]}

Keene, F. Richard ^{[1
]}

机构：

[1] James Cook Univ N Queensland, Sch Pharm & Mol Sci, Townsville, Qld 4811, Australia

来源：

CHEMICAL REVIEWS | 2006年 / 106卷 / 06期

关键词：

D O I：

10.1021/cr050010o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of the fundamental electron-transfer properties of trinuclear and tetranuclear complexes through the analysis of their intervalence charge transfer (IVCT) absorption characteristics. Emphasis is on the multiplicity of the IVCT bands, and the appearance of appreciable second-order interactions. Focus is also placed on the influence of the molecular shape of the assemblies on the nature of the IVCT. The stereochemical complexities inherent in the majority of species incorporating polyridyl ligands are also outlined.

引用

页码：2270 / 2298

页数：29

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