Preparation of highly active NiW hydrotreating model catalysts with 1,2-cyclohexanediamine-N,N,N′N′-tetraacetic acid (CyDTA) as a chelating agent

被引:29
作者
Kishan, G [1 ]
Coulier, L [1 ]
de Beer, VHJ [1 ]
van Veen, JAR [1 ]
Niemantsverdriet, JW [1 ]
机构
[1] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1039/b003272g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Changing the order in which oxidic W and Ni convert to sulfides by adding 1,2-cyclohexanediamine-N,N,N',N'-tetraacetic acid (CyDTA) as a chelating agent for nickel in the preparation of NiWS-SiO2 catalysts is the key ingredient in obtaining a high activity for thiophene hydrodesulfurization.
引用
收藏
页码:1103 / 1104
页数:2
相关论文
共 15 条
[11]   Highly active hydrotreatment catalysts prepared with chelating agents [J].
Shimizu, T ;
Hiroshima, K ;
Honma, T ;
Mochizuki, T ;
Yamada, M .
CATALYSIS TODAY, 1998, 45 (1-4) :271-276
[12]  
TAPSOE H, 1996, HYDROTREATING CATALY
[13]   DEPOSITION OF INORGANIC SALTS FROM SOLUTION ON FLAT SUBSTRATES BY SPIN-COATING - THEORY, QUANTIFICATION AND APPLICATION TO MODEL CATALYSTS [J].
VANHARDEVELD, RM ;
GUNTER, PLJ ;
VANIJZENDOORN, LJ ;
WIELDRAAIJER, W ;
KUIPERS, EW ;
NIEMANTSVERDRIET, JW .
APPLIED SURFACE SCIENCE, 1995, 84 (04) :339-346
[14]   A REAL SUPPORT EFFECT ON THE ACTIVITY OF FULLY SULFIDED COMOS FOR THE HYDRODESULFURIZATION OF THIOPHENE [J].
VANVEEN, JAR ;
GERKEMA, E ;
VANDERKRAAN, AM ;
KNOESTER, A .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (22) :1684-1686
[15]   Basic reaction steps in the sulfidation of crystalline MoO3 to MoS2 as studied by X-ray photoelectron and infrared emission spectroscopy [J].
Weber, T ;
Muijsers, JC ;
vanWolput, HJMC ;
Verhagen, CPJ ;
Niemantsverdriet, JW .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (33) :14144-14150