First optically active P*-chiral phosphapalladacycle

被引：33

作者：

Dunina, VV

Gorunova, ON

Kuz'mina, LG

Livantsov, MV

Grishin, YK

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(99)00403-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first cyclopalladated complex containing an asymmetric P*-donor atom in the phosphapalladacycle has been prepared in an enantiomerically pure state via resolution of diastereomeric (S)-prolinate derivatives of the racemic dimer. The absolute configuration of the P*-stereocenter (S-P) and the geometric configuration of the palladium environment (Z) were determined by an X-ray diffraction investigation of the less soluble diastereomer of the (S)-prolinate adduct. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

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页码：3951 / 3961

页数：11

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