Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

被引：1295

作者：

Brennfuehrer, Anne ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 23期

关键词：

aryl halides; carbon monoxide; carbonylation; homogeneous catalysis; palladium; CROSS-COUPLING REACTION; ALPHA-KETO ESTERS; ENANTIOSELECTIVE TOTAL-SYNTHESIS; GASEOUS CARBON-MONOXIDE; N-HETEROCYCLIC CARBENE; X-RAY-STRUCTURE; ORGANIC HALIDES; CONVENIENT SYNTHESIS; EFFICIENT SYNTHESIS; HYPERVALENT IODINE;

D O I：

10.1002/anie.200900013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalyzed carbonylation reactions of aromatic halides in the presence of various nucleophiles have undergone rapid development since the pioneering work of Heck and co-workers in 1974, such that nowadays a plethora of palladium catalysts are available for different carbonylative transformations. The carboxylic acid derivatives, aldehydes, and ketones prepared in this way are important intermediates in the manufacture of dyes, pharmaceuticals, agro-chemicals, and other industrial products. In this Review, the recent academic developments in this area and the first industrial processes are summarized. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4114 / 4133

页数：20

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