Facile synthesis of graphene-supported mesoporous Mn3O4 nanosheets with a high-performance in Li-ion batteries

被引:29
作者
Chen, Chao [1 ]
Jian, Hong [1 ]
Fu, Xinxin [1 ]
Ren, Zhimin [1 ]
Yan, Mi [1 ]
Qian, Guodong [1 ]
Wang, Zhiyu [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
CAPACITY ANODE MATERIAL; LITHIUM; LITHIATION; HYBRID;
D O I
10.1039/c3ra45976d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a room-temperature, facile and scalable strategy for the synthesis of Mn3O4 nanosheet/graphene nanocomposites. An important characteristic of these Mn3O4 nanosheets is their mesoporous nature and they have mesopores which are similar to 4 nm in size. Such nanocomposites exhibit a high performance in lithium-ion batteries by virtue of this advantageous structural feature.
引用
收藏
页码:5367 / 5370
页数:4
相关论文
共 25 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries [J].
Gao, Jie ;
Lowe, Michael A. ;
Abruna, Hector D. .
CHEMISTRY OF MATERIALS, 2011, 23 (13) :3223-3227
[3]   Electronic Origin for the Phase Transition from Amorphous LixSi to Crystalline Li15Si4 [J].
Gu, Meng ;
Wang, Zhiguo ;
Connell, Justin G. ;
Perea, Daniel E. ;
Lauhon, Lincoln J. ;
Gao, Fei ;
Wang, Chongmin .
ACS NANO, 2013, 7 (07) :6303-6309
[4]   Conflicting Roles of Nickel in Controlling Cathode Performance in Lithium Ion Batteries [J].
Gu, Meng ;
Belharouak, Ilias ;
Genc, Arda ;
Wang, Zhiguo ;
Wang, Dapeng ;
Amine, Khalil ;
Gao, Fei ;
Zhou, Guangwen ;
Thevuthasan, Suntharampillai ;
Baer, Donald R. ;
Zhang, Ji-Guang ;
Browning, Nigel D. ;
Liu, Jun ;
Wang, Chongmin .
NANO LETTERS, 2012, 12 (10) :5186-5191
[5]   In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix [J].
Gu, Meng ;
Li, Ying ;
Li, Xiaolin ;
Hu, Shenyang ;
Zhang, Xiangwu ;
Xu, Wu ;
Thevuthasan, Suntharampillai ;
Baer, Donald R. ;
Zhang, Ji-Guang ;
Liu, Jun ;
Wang, Chongmin .
ACS NANO, 2012, 6 (09) :8439-8447
[6]   In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode [J].
Huang, Jian Yu ;
Zhong, Li ;
Wang, Chong Min ;
Sullivan, John P. ;
Xu, Wu ;
Zhang, Li Qiang ;
Mao, Scott X. ;
Hudak, Nicholas S. ;
Liu, Xiao Hua ;
Subramanian, Arunkumar ;
Fan, Hongyou ;
Qi, Liang ;
Kushima, Akihiro ;
Li, Ju .
SCIENCE, 2010, 330 (6010) :1515-1520
[7]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[8]   Rapid microwave-assisted synthesis of Mn3O4-graphene nanocomposite and its lithium storage properties [J].
Li, Li ;
Guo, Zaiping ;
Du, Aijun ;
Liu, Huakun .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (08) :3600-3605
[9]   Three-dimensional nanohybrids of Mn3O4/ordered mesoporous carbons for high performance anode materials for lithium-ion batteries [J].
Li, Zhaoqiang ;
Liu, Ningning ;
Wang, Xuekun ;
Wang, Changbin ;
Qi, Yongxin ;
Yin, Longwei .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (32) :16640-16648
[10]   TiO2 Nanocrystals Grown on Graphene as Advanced Photocatalytic Hybrid Materials [J].
Liang, Yongye ;
Wang, Hailiang ;
Casalongue, Hernan Sanchez ;
Chen, Zhuo ;
Dai, Hongjie .
NANO RESEARCH, 2010, 3 (10) :701-705