One-Step Pyro-Synthesis of a Nanostructured Mn3O4/C Electrode with Long Cycle Stability for Rechargeable Lithium-Ion Batteries

被引：40

作者：

Alfaruqi, Muhammad Hilmy ^{[1
]}

Gim, Jihyeon ^{[1
]}

Kim, Sungjin ^{[1
]}

Song, Jinju ^{[1
]}

Pham Tung Duong ^{[1
]}

Jo, Jeonggeun ^{[1
]}

Baboo, Joseph Paul ^{[1
]}

Xiu, Zhiliang ^{[1
]}

Mathew, Vinod ^{[1
]}

Kim, Jaekook ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Mat Sci & Engn, 300 Yongbong Dong, Kwangju 500757, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

anode materials; electrochemistry; Li-ion batteries; nanostructures; pyro-synthesis; CAPACITY ANODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; NEGATIVE-ELECTRODE; FACILE SYNTHESIS; RATE CAPABILITY; STORAGE; OXIDATION; STRATEGY; CATHODE; HYBRID;

D O I：

10.1002/chem.201504609

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A nanostructured Mn3O4/C electrode was prepared by a one-step polyol-assisted pyro-synthesis without any post-heat treatments. The as-prepared Mn3O4/C revealed nanostructured morphology comprised of secondary aggregates formed from carbon-coated primary particles of average diameters ranging between 20 and 40nm, as evidenced from the electron microscopy studies. The N-2 adsorption studies reveal a hierarchical porous feature in the nanostructured electrode. The nanostructured morphology appears to be related to the present rapid combustion strategy. The nanostructured porous Mn3O4/C electrode demonstrated impressive electrode properties with reversible capacities of 666mAhg(-1) at a current density of 33mAg(-1), good capacity retentions (1141mAhg(-1) with 100% Coulombic efficiencies at the 100(th) cycle), and rate capabilities (307 and 202mAhg(-1) at 528 and 1056mAg(-1), respectively) when tested as an anode for lithium-ion battery applications.

引用

页码：2039 / 2045

页数：7

共 46 条

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Additives-containing functional electrolytes for suppressing electrolyte decomposition in lithium-ion batteries [J].