Synthesis of new chiral benzylically substituted P,N-ligands and their applications in the asymmetric Heck reaction

被引：40

作者：

Hou, XL ^{[1
]}

Dong, DX ^{[1
]}

Yuan, K ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 14期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetasy.2004.05.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new chiral P,N-ligands with substituents at the benzylic position has been prepared. Their high catalytic activity is shown in the Pd-catalyzed asymmetric Heck reaction and allylic substitution reaction. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2189 / 2191

页数：3

共 34 条

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You, SL ;

Hou, XL ;

Dai, LX ;

Zhu, XZ .

ORGANIC LETTERS, 2001, 3 (02) :149-151

[32] Synthesis of planar chiral selenide derivatives of ferrocenyl-oxazoline and their application in enantioselective palladium catalyzed allylic substitution reaction [J].

You, SL ;

Hou, XL ;

Dai, LX .

TETRAHEDRON-ASYMMETRY, 2000, 11 (07) :1495-1500

[33] Highly regio- and enantioselective Pd-catalyzed allylic alkylation and amination of monosubstituted allylic acetates with novel ferrocene P,N-ligands [J].

You, SL ;

Zhu, XZ ;

Luo, YM ;

Hou, XL ;

Dai, LX .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (30) :7471-7472

[34]

ZHOU QL, 1994, TETRAHEDRON, V50, P4467

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