O2 chemistry of dicopper complexes with alkyltriamine ligands.: Comparing synergistic effects on O2 binding

被引：19

作者：

Company, Anna

Lamata, Diana

Poater, Albert

Sola, Miquel

Rybak-Akimova, Elena V. ^{[1
]}

Que, Lawrence, Jr.

Fontrodona, Xavier

Parella, Teodor

Llobet, Antoni

Costas, Miquel

机构：

[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA

[2] Univ Girona, Dept Quim, E-17071 Girona, Catalonia, Spain

[3] Univ Girona, Inst Quim Computac, E-17071 Girona, Catalonia, Spain

[4] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[5] Univ Girona, Serv Cient Tecn, E-17071 Girona, Spain

[6] Univ Autonoma Barcelona, Serv RMN, E-08193 Bellaterra, Spain

[7] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 14期

关键词：

D O I：

10.1021/ic0602446

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O-2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O-2 activation.

引用

收藏

页码：5239 / 5241

页数：3

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