Simultaneous enzymatic ring opening polymerisation and RAFT-mediated polymerisation in supercritical CO2

被引：60

作者：

Thurecht, Kristofer J.

Gregory, Andrew M.

Villarroya, Silvia

Zhou, Jiaxiang

Heise, Andreas

Howdle, Steven M.

机构：

[1] Univ Nottingham, Sch Chem, Nottingham, England

[2] Eindhoven Univ Technol, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 42期

关键词：

D O I：

10.1039/b611626d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report presents the first simultaneous, metal-free synthesis of block copolymers through combination of enzymatic ring-opening polymerisation of epsilon-caprolactone with RAFT-mediated controlled radical polymerisation of styrene.

引用

页码：4383 / 4385

页数：3

共 9 条

[1] Investigation of factors influencing the chemoenzymatic synthesis of block copolymers [J].

de Geus, M ;

Peeters, J ;

Wolffs, M ;

Hermans, T ;

Palmans, ARA ;

Koning, CE ;

Heise, A .

MACROMOLECULES, 2005, 38 (10) :4220-4225

[2] Can block copolymers be synthesized by a single-step chemoenzymatic route in supercritical carbon dioxide? [J].

Duxbury, CJ ;

Wang, WX ;

de Geus, M ;

Heise, A ;

Howdle, SM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (08) :2384-2385

[3] Shell-cross-linked vesicles synthesized from block copolymers of poly(D,L-lactide) and poly (N-isopropyl acrylamide) as thermoresponsive nanocontainers [J].

Hales, M ;

Barner-Kowollik, C ;

Davis, TP ;

Stenzel, MH .

LANGMUIR, 2004, 20 (25) :10809-10817

[4] Enhancing drug function [J].

Hubbell, JA .

SCIENCE, 2003, 300 (5619) :595-596

[5] Cascade synthesis of chiral block copolymers combining lipase catalyzed ring opening polymerization and atom transfer radical polymerization [J].

Peeters, J ;

Palmans, ARA ;

Veld, M ;

Scheijen, F ;

Heise, A ;

Meijer, EW .

BIOMACROMOLECULES, 2004, 5 (05) :1862-1868

[6] Amphiphilic block copolymers based on poly (2-acryloyloxyethyl phosphorylcholine) prepared via RAFT polymerisation as biocompatible nanocontainers [J].

Stenzel, MH ;

Barner-Kowollik, C ;

Davis, TP ;

Dalton, HM .

MACROMOLECULAR BIOSCIENCE, 2004, 4 (04) :445-453

[7] One-pot chemoenzymatic cascade polymerization under kinetic resolution conditions [J].

van As, BAC ;

Thomassen, P ;

Kalra, B ;

Gross, RA ;

Meijer, EW ;

Palmans, ARA ;

Heise, A .

MACROMOLECULES, 2004, 37 (24) :8973-8977

[8] Analysis of organosilicone copolymers by gradient polymer elution chromatography with evaporative light scattering detection [J].

Verhelst, V ;

Vandereecken, P .

JOURNAL OF CHROMATOGRAPHY A, 2000, 871 (1-2) :269-277

[9] One-step chemoenzymatic synthesis of poly(ε-caprolactone-block-methyl methacrylate) in supercritical CO2 [J].

Zhou, Jiaxiang ;

Villarroya, Silvia ;

Wang, Wenxin ;

Wyatt, Mark F. ;

Duxbury, Christopher J. ;

Thurecht, Kristofer J. ;

Howdle, Steven M. .

MACROMOLECULES, 2006, 39 (16) :5352-5358

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