Analysis of the reactivity of the dithioacetal mono-S-oxide 1-deoxy-1-ethylsulfinyl-1-ethylthio-3,4-O-isopropylidene-D-erythritol under different conditions of reduction

被引：5

作者：

ArroyoGomez, Y ^{[1
]}

LopezSastre, JA ^{[1
]}

RodriguezAmo, JF ^{[1
]}

SanzTejedor, MA ^{[1
]}

机构：

[1] UNIV VALLADOLID,DEPT QUIM ORGAN,INST INVEST & DESARROLLO TECNOL IND,E-47011 VALLADOLID,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 24期

关键词：

D O I：

10.1039/p19960002933

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chemistry of dithioacetal mono-S-oxides has not been studied very frequently. Their usual chemistry aims at recovering the carbonyl function by a sequence of reduction and hydrolysis. The results of the transformation of the dithioacetal mono-S-oxides of 1-deoxy-1-ethylsulfinyl-1-ethylthio-3,4-O-isopropylidene-D-erythritol, 2, under different reduction conditions, are reported in this paper. We also report how the coexistence of functional groups influences the resulting products. Hence, reductions with LiAlH4, Ph(3)P, (Me(2)N)(3)P, (CF3CO)(2)O-NaI and AcONa-Ac2O under Pummerer-type rearrangements have been studied.

引用

页码：2933 / 2936

页数：4

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