Preparation of a Si(111):GaSe van der Waals surface termination by selenization of a monolayer Ga on Si(111)

被引:16
作者
Fritsche, R
Wisotzki, E
Thissen, A
Islam, ABMO
Klein, A
Jaegermann, W
Rudolph, R
Tonti, D
Pettenkofer, C
机构
[1] TH Darmstadt, Surface Sci Div, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany
[2] Hahn Meitner Inst Berlin GmbH, Solar Energy Res SE6, D-14109 Berlin, Germany
关键词
photoelectron spectroscopy; low energy electron diffraction (LEED); silicon; epitaxy;
D O I
10.1016/S0039-6028(02)01851-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A Ga-Se half-sheet van der Waals surface termination on Si(111) is prepared in a two step process involving selenization of a monolayer gallium on the surface. Substrate and film growth were investigated in situ by high-resolution synchrotron X-ray photoemission and low-energy electron diffraction. Due to repeated reorganizing of the Si surface atoms and etching of Ga by excess Se it is generally difficult to achieve a complete surface coverage by GaSe by this preparation procedure. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:296 / 304
页数:9
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