Reductions of 1,3-dicarbonyl systems with ruthenium-biarylbisphosphine catalysts

被引：86

作者：

Ager, DJ

Laneman, SA

机构：

[1] NSC Technologies, A Unit of Monsanto, Mount Prospect, IL 60056

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(97)00455-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A variety of biarylbisphosphine-based ligands for ruthenium have been used to catalyze the asymmetric hydrogenation of beta-dicarbonyl systems. The method of preparation of the catalyst system plays an important role in the stereochemical outcome of the reaction as well as the reaction conditions required. The mechanism of the reaction has not been fully elucidated, but some insight has been gained. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：3327 / 3355

页数：29

共 93 条

[61] BINAP - AN EFFICIENT CHIRAL ELEMENT FOR ASYMMETRIC CATALYSIS
NOYORI, R
TAKAYA, H
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (10) : 345 - 350
[62] NOYORI R, 1993, Patent No. 5198562
[63] BEYOND NATURES CHIRAL POOL - ENANTIOSELECTIVE CATALYSIS IN INDUSTRY
NUGENT, WA
RAJANBABU, TV
BURK, MJ
[J]. SCIENCE, 1993, 259 (5094) : 479 - 483
[64] An anionic dinuclear BINAP-ruthenium(II) complex: Crystal structure of [NH(2)Et(2)][{RuCl((R)-p-MeO-BINAP)}(2)(mu-Cl)(3)] and its use in asymmetric hydrogenation
Ohta, T
Tonomura, Y
Nozaki, K
Takaya, H
Mashima, K
[J]. ORGANOMETALLICS, 1996, 15 (06) : 1521 - 1523
[65] RECENT ADVANCES IN CATALYTIC ASYMMETRIC REACTIONS PROMOTED BY TRANSITION-METAL COMPLEXES
OJIMA, I
CLOS, N
BASTOS, C
[J]. TETRAHEDRON, 1989, 45 (22) : 6901 - 6939
[66] CHIRAL SEMICORRINS AND RELATED NITROGEN-HETEROCYCLES AS LIGANDS IN ASYMMETRIC CATALYSIS
PFALTZ, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (06) : 339 - 345
[67] ROSEN T, 1986, TETRAHEDRON, V42, P4808
[68] SYNTHESIS OF A CHIRAL SYNTHON FOR THE LACTONE PORTION OF COMPACTIN AND MEVINOLIN
ROTH, BD
ROARK, WH
[J]. TETRAHEDRON LETTERS, 1988, 29 (11) : 1255 - 1258
[69] SAYO N, 1990, Patent No. 4916252
[70] Sayo N., 1991, US, Patent No. 4981992

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