Relaxorlike dielectric properties and history-dependent effects in the lead-free K0.5Na0.5NbO3-SrTiO3 ceramic system

被引:76
作者
Bobnar, V [1 ]
Bernard, J [1 ]
Kosec, M [1 ]
机构
[1] Jozef Stefan Inst, SI-1001 Ljubljana, Slovenia
关键词
D O I
10.1063/1.1779947
中图分类号
O59 [应用物理学];
学科分类号
摘要
Typical relaxorlike dielectric properties, such as broad dispersive dielectric maximum, Vogel-Fulcher temperature dependence of the characteristic relaxation frequency, and paraelectric-to-glass crossover in the temperature dependence of the dielectric nonlinearity, have been detected in the derived lead-free K0.5Na0.5NbO3-SrTiO3 ceramic system. Relatively large values of the dielectric constant, being almost independent of the frequency in the range of 100 Hz-1 MHz, suggest possible applications based on this environmentally friendly system. Furthermore, the history-dependent effects, such as aging of the dielectric constant and fatigue of the polarization switching, are much weaker than in some widely used lead-based relaxors. (C) 2004 American Institute of Physics.
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页码:994 / 996
页数:3
相关论文
共 17 条
[1]   Crossover from glassy to inhomogeneous-ferroelectric nonlinear dielectric response in relaxor ferroelectrics [J].
Bobnar, V ;
Kutnjak, Z ;
Pirc, R ;
Blinc, R ;
Levstik, A .
PHYSICAL REVIEW LETTERS, 2000, 84 (25) :5892-5895
[2]   Dielectric properties of relaxor-like vinylidene fluoride - Trifluoroethylene-based electroactive polymers [J].
Bobnar, V ;
Vodopivec, B ;
Levstik, A ;
Kosec, M ;
Hilczer, B ;
Zhang, QM .
MACROMOLECULES, 2003, 36 (12) :4436-4442
[3]   Ferroelectric fatigue of Pb(Zr,Ti)O3 thin films measured in atmospheres of varying oxygen concentration [J].
Brazier, M ;
Mansour, S ;
McElfresh, M .
APPLIED PHYSICS LETTERS, 1999, 74 (26) :4032-4033
[4]   Discrimination between bulk and interface scenarios for the suppression of the switchable polarization (fatigue) in Pb(Zr,Ti)O3 thin films capacitors with Pt electrodes [J].
Colla, EL ;
Taylor, DV ;
Tagantsev, AK ;
Setter, N .
APPLIED PHYSICS LETTERS, 1998, 72 (19) :2478-2480
[5]   LONG-TIME RELAXATION OF THE DIELECTRIC RESPONSE IN LEAD MAGNONIOBATE [J].
COLLA, EV ;
KOROLEVA, EY ;
OKUNEVA, NM ;
VAKHRUSHEV, SB .
PHYSICAL REVIEW LETTERS, 1995, 74 (09) :1681-1684
[6]  
CROSS LE, 1987, FERROELECTRICS, V76, P241, DOI 10.2109/jcersj.99.829
[7]   MINIMIZATION OF FATIGUE IN FERROELECTRIC-FILMS [J].
DESU, SB .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1995, 151 (02) :467-480
[8]   New lead-free relaxors based on the K0.5Na0.5Nb0.30-SrTi0.3 solid solution [J].
Kosec, M ;
Bobnar, V ;
Hrovat, M ;
Bernard, J ;
Malic, B ;
Holc, J .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (06) :1849-1854
[9]   Slow dynamics and ergodicity breaking in a lanthanum-modified lead zirconate titanate relaxor system [J].
Kutnjak, Z ;
Filipic, C ;
Pirc, R ;
Levstik, A ;
Farhi, R ;
El Marssi, M .
PHYSICAL REVIEW B, 1999, 59 (01) :294-301
[10]  
KUTNJAK Z, 2000, FERROELECTRICS, V240, P273