From interfaces to surfaces: soft x-ray spectromicroscopy investigations of diindenoperylene thin films on gold

被引:3
作者
Casu, M. B. [1 ]
Schuster, B-E [1 ]
Biswas, I. [1 ]
Nagel, M. [1 ]
Nagel, P. [2 ]
Schuppler, S. [2 ]
Chasse, T. [1 ]
机构
[1] Univ Tubingen, Inst Phys & Theoret Chem, D-72076 Tubingen, Germany
[2] Forschungszentrum Karlsruhe, Inst Festkorperphys, D-76021 Karlsruhe, Germany
关键词
THERMAL-STABILITY; GROWTH; MORPHOLOGY; MOLECULES; AG(111); PTCDA;
D O I
10.1088/0953-8984/21/31/314017
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present the results of photoemission electron microscopy investigations on diindenoperylene (DIP) thin films deposited on polycrystalline gold, prepared in order to have a roughness much larger than the molecular size. Our investigations revealed the ability of the DIP molecule to form well-organized films, exhibiting a different molecular orientation with respect to the already known lambda and sigma phases. In locally thicker film regions, the energy of the films is minimized by a molecular arrangement that has an asymptotic tendency to the sigma phase.
引用
收藏
页数:5
相关论文
共 16 条
[1]   Buried interfacial layer of highly oriented molecules in copper phthalocyanine thin films on polycrystalline gold [J].
Biswas, Indro ;
Peisert, Heiko ;
Nagel, Mathias ;
Casu, Maria Benedetta ;
Schuppler, Stefan ;
Nagel, Peter ;
Pellegrin, Eric ;
Chasse, Thomas .
JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (17)
[2]   Photoemission electron microscopy of diindenoperylene thin films [J].
Casu, M. B. ;
Biswas, I. ;
Nagel, M. ;
Nagel, P. ;
Schuppler, S. ;
Chasse, T. .
PHYSICAL REVIEW B, 2008, 78 (07)
[3]   A high-resolution near-edge x-ray absorption fine structure investigation of the molecular orientation in the pentacene/poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) pentacene/system [J].
Casu, M. B. ;
Cosseddu, P. ;
Batchelor, D. ;
Bonfiglio, A. ;
Umbach, E. .
JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (01)
[4]   Molecular orientation in diindenoperylene thin films deposited on polycrystalline gold [J].
Casu, M. B. ;
Biswas, I. ;
Schuster, B. -E. ;
Nagel, M. ;
Nagel, P. ;
Schuppler, S. ;
Chasse, T. .
APPLIED PHYSICS LETTERS, 2008, 93 (02)
[5]   Temperature-dependent morphology and structure of ordered 3,4,9,10-perylene-tetracarboxylicacid-dianhydride (PTCDA) thin films on Ag(111) [J].
Chkoda, L ;
Schneider, M ;
Shklover, V ;
Kilian, L ;
Sokolowski, M ;
Heske, C ;
Umbach, E .
CHEMICAL PHYSICS LETTERS, 2003, 371 (5-6) :548-552
[6]   Interplay between morphology, structure, and electronic properties at diindenoperylene-gold interfaces -: art. no. 115428 [J].
Dürr, AC ;
Koch, N ;
Kelsch, M ;
Rühm, A ;
Ghijsen, J ;
Johnson, RL ;
Pireaux, JJ ;
Schwartz, J ;
Schreiber, F ;
Dosch, H ;
Kahn, A .
PHYSICAL REVIEW B, 2003, 68 (11)
[7]  
Dürr AC, 2002, ADV MATER, V14, P961
[8]   Growth of pentacene on clean and modified gold surfaces [J].
Kaefer, Daniel ;
Ruppel, Lars ;
Witte, Gregor .
PHYSICAL REVIEW B, 2007, 75 (08)
[9]   Charge carrier transport in organic semiconductors [J].
Karl, N .
SYNTHETIC METALS, 2003, 133 :649-657
[10]   Growth mode and molecular orientation of phthalocyanine molecules on metal single crystal substrates: A NEXAFS and XPS study [J].
Kera, S ;
Casu, MB ;
Bauchspiess, KR ;
Batchelor, D ;
Schmidt, T ;
Umbach, E .
SURFACE SCIENCE, 2006, 600 (05) :1077-1084