Template synthesis of a polyiodide belt at a metal complex cation: Structure of [([16]aneS(4))M-I-M([16]aneS(4))](3+)[I-5(-)]2I(-) (M=Pd, Pt) incorporating asymmetric linear M-I-M bridge ([16]aneS(4)=1,5,9,13-tetrathiacyclohexadecane)

被引：27

作者：

Blake, AJ

Lippolis, V

Parsons, S

Schroder, M

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 18期

关键词：

D O I：

10.1039/cc9960002207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [M([16]aneS(4))[PF6](2) with NBu(4)(n)I(3) affords the binuclear species [([16]aneS(4))M-I-M([16]aneS(4))](3+) (M = Pd, Pt) incorporating a highly unusual linear M-I-M moiety within a conformationally constrained environment: the counter anion, which can be regarded formally as two I-5(-) and one I- or alternatively as two I-3(-), two I-2 and one I-, forms a belt around the complex cation with the metal-bridging I- placed at its centre.

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页码：2207 / 2208

页数：2

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