First high-resolution Raman spectrum and analysis of the ν5 bending fundamental of SF6

被引：19

作者：

Boudon, V

Bermejo, D

机构：

[1] Univ Bourgogne, Phys Lab, CNRS, UMR 5027, F-21078 Dijon, France

[2] CSIC, Inst Estructura Mat, E-28006 Madrid, Spain

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2002年 / 213卷 / 02期

关键词：

molecular spectroscopy; Raman; spherical top; sulfur hexafluoride;

D O I：

10.1006/jmsp.2002.8552

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The high-resolution Raman spectrum of the Q, R, and S branches of the v(5) bending fundamental of SF6 has been recorded at a temperature of 195 K (dry ice) and a pressure of 39 mbar. This is the first study ever performed of a v5 band of an XY6 molecule. It has been analyzed thanks to the HTDS software (http://www.u-bourgogne.fr/LPUB/shTDS.html) developed in Dijon. This contribution should be of help in understanding the role hot bands in the strong absorbing v(3) region. (C) 2002 Elsevier Science (USA).

引用

收藏

页码：139 / 144

页数：6

相关论文

共 32 条

[1] ANALYSIS OF THE RAMAN-SPECTRUM OF SF6 [J].

ABOUMAJD, A ;

BERGER, H ;

SAINTLOUP, R .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1979, 78 (03) :486-492

[2] New accurate fit of an extended set of saturation data for the ν3 band of SF6:: Comparison of Hamiltonians in the spherical and cubic tensor formalisms [J].

Acef, O ;

Bordé, CJ ;

Clairon, A ;

Pierre, G ;

Sartakov, B .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2000, 199 (02) :188-204

[3]

[Anonymous], 1992, Spherical Top Spectra

[4] HIGH-RESOLUTION QUASI-CONTINUOUS WAVE INVERSE RAMAN SPECTROMETER - SPECTRUM OF CH3D IN THE C-D STRETCHING REGION [J].

BERMEJO, D ;

SANTOS, J ;

CANCIO, P ;

DOMENECH, JL ;

DOMINGO, C ;

ORZA, JM ;

ORTIGOSO, J ;

ESCRIBANO, R .

JOURNAL OF RAMAN SPECTROSCOPY, 1990, 21 (03) :197-201

[5] Simultaneous analysis of the ν2 Raman and ν2+ν6 infrared spectra of the SF6 molecule [J].

Bermejo, D ;

Martínez, RZ ;

Loubignac, E ;

Boudon, V ;

Pierre, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2000, 201 (01) :164-171

[6] High-resolution jet-cooled spectroscopy of SF6:: The ν2+ν6 combination band of 32SF6 and the ν3 band of the rare isotopomers [J].

Boudon, V ;

Hepp, M ;

Herman, M ;

Pak, I ;

Pierre, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1998, 192 (02) :359-367

[7] High-resolution spectroscopy and analysis of the ν4 bending region of SF6 near 615 cm-1 [J].

Boudon, V ;

Pierre, G ;

Bürger, H .

JOURNAL OF MOLECULAR SPECTROSCOPY, 2001, 205 (02) :304-311

[8]

BOUDON V, 2002, IN PRESS TRANSWORLD

[9] Development of the dipole moment and polarizability operators of octahedral molecules [J].

Cheblal, N ;

Loëte, M ;

Boudon, V .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1999, 197 (02) :222-231

[10] RAMAN SPECTRA OF MOF6, TCF6, REF6, UF6, SF6, SEF6, AND TEF6 IN VAPOR STATE [J].

CLAASSEN, HH ;

GOODMAN, GL ;

HOLLOWAY, JH ;

SELIG, H .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (01) :341-&

← 1 2 3 4 →