syn- and anti-benzotris(norbornadiene)s

被引:23
作者
Durr, R [1 ]
DeLucchi, O [1 ]
Cossu, S [1 ]
Lucchini, V [1 ]
机构
[1] UNIV CA FOSCARI VENEZIA,DIPARTIMENTO SCI AMBIENTALI,I-30123 VENICE,ITALY
关键词
D O I
10.1039/cc9960002447
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hitherto unknown syn and anti isomers of benzotris(norbornadiene) 7, the only molecules that include both features known to lead to bond length alternation in benzenes, i.e. bicyclic ring strain and pi-pi interaction, have been synthesized from 2,3-dibromonorbornadiene using butyllithium and copper(I) iodide.
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页码:2447 / 2448
页数:2
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