Cationic Rh-bisphosphine-diolefin complexes as precatalysts for enantioselective catalysis - what information do single crystal structures contain regarding product chirality?

被引：29

作者：

Drexler, HJ ^{[1
]}

Zhang, SL ^{[1
]}

Sun, AL ^{[1
]}

Spannenberg, A ^{[1
]}

Arrieta, A ^{[1
]}

Preetz, A ^{[1
]}

Heller, D ^{[1
]}

机构：

[1] Univ Rostock eV, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 14期

关键词：

D O I：

10.1016/j.tetasy.2004.06.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For all five-membered Rh-bisphosphine-diolefin complexes of the type [Rh(PP)(diolefin)](+) as precursors for enanatioselective catalysis in the Cambridge Structural Database both the bite angle and the rotation of the diolefin are compiled and discussed, in relation to the product configuration. The bite angles are narrowly distributed and do not lead to a correlation with the product configuration. Additionally, it is not possible to discern a clear relation between the direction of rotation of the diolefin in the precatalyst and the product configuration. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2139 / 2150

页数：12

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