On studies of oxide solubilities in melts based on alkaline halides

被引：23

作者：

Cherginets, VL

机构：

[1] Inst. Single Crystals Natl. Acad. S., Kharkov, 310001

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 23-24期

关键词：

oxide solubilities; alkaline halides; molten salts;

D O I：

10.1016/S0013-4686(97)00031-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Studies of oxide solubilities (methods and results) in molten alkaline chlorides are considered. The scatter of literature data on oxide solubilities in molten KCl-NaCl has been explained by the effect of crystal grain sizes on their solubilities according to the Ostvald-Freindlich rule. Author's results of systematic oxide solubilities' studies in molten alkaline halides (KCl-NaCl, CsCl-KCl-NaCl, CsBr-KBr, CsI) are considered. Oxide solubilities in molten alkaline halides (pP) have been found to vary linearly with corresponding cation radii; such plots might be proposed for estimations of oxide solubilities in molten alkaline halides. (C) 1997 Elsevier Science Ltd.

引用

页码：3619 / 3627

页数：9

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