Monohydroxylation of cyclic and acyclic β-keto esters with molecular oxygen catalyzed by cobalt(II) chloride in neutral conditions

被引：39

作者：

Baucherel, X ^{[1
]}

Levoirier, E ^{[1
]}

Uziel, J ^{[1
]}

Juge, S ^{[1
]}

机构：

[1] Univ Cergy Pontoise, Unite Mixte Synthese Organ Select & Chim Organome, ESCOM, CNRS,EP 1822, F-95031 Cergy Pontoise, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 09期

关键词：

oxygen; hydroxylation; catalysis; keto esters;

D O I：

10.1016/S0040-4039(99)02275-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclic and acyclic α-alkyl-α-hydroxy-β-keto esters 2 were obtained with 50-100% isolated yields from the corresponding β-keto esters 1 by oxidation with molecular oxygen in a mixture of CH3CN/i-PrOH and in the presence of cobalt(II) chloride. (C) 2000 Elsevier Science Ltd.

引用

页码：1385 / 1387

页数：3

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