Neutral five-co-ordinate gallium(III) and indium(III) complexes derived from sulfur ligands

被引：30

作者：

Bhattacharya, S

Seth, N

Srivastava, DK

Gupta, VD

Noth, H

ThomannAlbach, M

机构：

[1] BANARAS HINDU UNIV,FAC SCI,DEPT CHEM,VARANASI 221005,UTTAR PRADESH,INDIA

[2] UNIV MUNICH,INST INORGAN CHEM,D-80333 MUNICH,GERMANY

[3] SANT LONGOWAL INST ENGN & TECH,DEPT CHEM,LONGOWAL 148106,PUNJAB,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 13期

关键词：

D O I：

10.1039/dt9960002815

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five-co-ordinated gallium(III) and indium(III) complexes, GaCl[PhC(S)CHC(O)Ph](2), GaCl(S(2)CNR(2))(2) (R = Me, Pr-i or NR(2) = pyrrolyl) and InCl(S2CNPr2i)(2), have been synthesized and characterized. X-Ray crystallographic studies revealed a trigonal-bipyramidal structure for GaCl[PhC(S)CHC(O)Ph](2) and square-pyramidal structures for GaCl(S(2)CNMe(2))(2) and InCl(S2CNPr2i)(2). Also, Ga(S2CNC4H4)(3) has been synthesized. Its molecular structure shows a GaS6 core approaching a trigonal-prismatic geometry.

引用

页码：2815 / 2820

页数：6

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[21]

Johnson C. K., 1976, ORNL5138 ORTEP

[22] THE STRUCTURE OF TRICHLOROBIS(TRIMETHYLAMINE)INDIUM(III) [J].