High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation

被引：212

作者：

Gao, Yao ^{[1
,2
]}

Zhang, Xiaojie ^{[1
]}

Tian, Hongkun ^{[1
]}

Zhang, Jidong ^{[1
]}

Yan, Donghang ^{[1
]}

Geng, Yanhou ^{[1
,3
,4
]}

Wang, Fosong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China

[4] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 42期

基金：

中国国家自然科学基金;

关键词：

FIELD-EFFECT TRANSISTORS; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; DIRECT (HETERO)ARYLATION; DIRECT HETEROARYLATION; EFFICIENT APPROACH; BUILDING-BLOCK; SOLAR-CELLS; HIGH HOLE; COPOLYMERS;

D O I：

10.1002/adma.201502896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diketopyrrolopyrrole-based conjugated polymer, PDPP-4FTVT, which exhibits ambipolar transport behavior in air with hole and electron mobilities up to 3.40 and 5.86 cm(2) V-1 s(-1), respectively, is synthesized via direct arylation polycondensation. Incorporation of F-atoms in beta-positions of thiophene rings dramatically improves the efficiency of direct arylation polycondensation. [GRAPHICS] .

引用

页码：6753 / +

页数：8

共 57 条

[1] Easy and versatile synthesis of new poly(thieno[3,4-d]thiazole)s [J].

Allard, Nicolas ;

Najari, Ahmed ;

Pouliot, Jean-Remi ;

Pron, Agnieszka ;

Grenier, Francois ;

Leclerc, Mario .

POLYMER CHEMISTRY, 2012, 3 (10) :2875-2879

[2] Investigation of Structure-Property Relationships in Diketopyrrolopyrrole-Based Polymer Semiconductors via Side-Chain Engineering [J].

Back, Jang Yeol ;

Yu, Hojeong ;

Song, Inho ;

Kang, Il ;

Ahn, Hyungju ;

Shin, Tae Joo ;

Kwon, Soon-Ki ;

Oh, Joon Hak ;

Kim, Yun-Hi .

CHEMISTRY OF MATERIALS, 2015, 27 (05) :1732-1739

[3] Toward Printed Integrated Circuits based on Unipolar or Ambipolar Polymer Semiconductors [J].

Baeg, Kang-Jun ;

Caironi, Mario ;

Noh, Yong-Young .

ADVANCED MATERIALS, 2013, 25 (31) :4210-4244

[4] Thieno-, Furo-, and Selenopheno[3,4-c]pyrrole-4,6-dione Copolymers: Effect of the Heteroatom on the Electrooptical Properties [J].

Beaupre, Serge ;

Pron, Agnieszka ;

Drouin, Simon H. ;

Najari, Ahmed ;

Mercier, Lauren G. ;

Robitaille, Amelie ;

Leclerc, Mario .

MACROMOLECULES, 2012, 45 (17) :6906-6914

[5] Low-Cost Synthesis and Physical Characterization of Thieno[3,4-c]pyrrole-4,6-dione-Based Polymers [J].

Berrouard, Philippe ;

Dufresne, Stephane ;

Pron, Agnieszka ;

Veilleux, Justine ;

Leclerc, Mario .

JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (18) :8167-8173

[6] Synthesis of 5-Alkyl[3,4-c]thienopyrrole-4,6-dione-Based Polymers by Direct Heteroarylation [J].

Berrouard, Philippe ;

Najari, Ahmed ;

Pron, Agnieszka ;

Gendron, David ;

Morin, Pierre-Olivier ;

Pouliot, Jean-Remi ;

Veilleux, Justine ;

Leclerc, Mario .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (09) :2068-2071

[7] Highly p-Extended Copolymers with Diketopyrrolopyrrole Moieties for High-Performance Field-Effect Transistors [J].

Chen, Huajie ;

Guo, Yunlong ;

Yu, Gui ;

Zhao, Yan ;

Zhang, Ji ;

Gao, Dong ;

Liu, Hongtao ;

Liu, Yunqi .

ADVANCED MATERIALS, 2012, 24 (34) :4618-4622

[8] Semiconducting Polymers Prepared by Direct Arylation Polycondensation [J].

Facchetti, Antonio ;

Vaccaro, Luigi ;

Marrocchi, Assunta .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (15) :3520-3523

[9] Synthesis of Thiophene- and Bithiophene-Based Alternating Copolymers via Pd-Catalyzed Direct C-H Arylation [J].

Fujinami, Yohei ;

Kuwabara, Junpei ;

Lu, Wei ;

Hayashi, Hideki ;

Kanbara, Takaki .

ACS MACRO LETTERS, 2012, 1 (01) :67-70

[10] Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates [J].

Gorelsky, Serge I. ;

Lapointe, David ;

Fagnou, Keith .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10848-+

← 1 2 3 4 5 6 →