Highly p-Extended Copolymers with Diketopyrrolopyrrole Moieties for High-Performance Field-Effect Transistors

被引：742

作者：

Chen, Huajie ^{[1
]}

Guo, Yunlong ^{[1
]}

Yu, Gui ^{[1
]}

Zhao, Yan ^{[1
]}

Zhang, Ji ^{[1
]}

Gao, Dong ^{[1
]}

Liu, Hongtao ^{[1
]}

Liu, Yunqi ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 34期

基金：

中国国家自然科学基金;

关键词：

p-extended copolymers; diketopyrrolopyrrole moieties; high-performance; air-stability; transistors; THIN-FILM TRANSISTORS; CHARGE-CARRIER MOBILITY; SEMICONDUCTING POLYMERS; CONJUGATED POLYMERS; SIDE-CHAINS; SOLAR-CELLS; AMBIPOLAR; ACCEPTOR; DONOR; HOLE;

D O I：

10.1002/adma.201201318

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two donor-acceptor (D-A) copolymer PDVTs based on diketopyrrolopyrole and (E)-2-(2-(thiophen-2-yl)vinyl)thiophene (TVT) units are synthesized for solution-processed field-effect transistors (FETs). The highly π-extended TVT units strengthen the coplanarity of the polymer backbone. FETs based on PDVTs show high mobilities above 2.0 cm2 V-1 s-1 with a current on/off ratio of 105-107, high shelf storage, and operation stability. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4618 / 4622

页数：5

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