C-C coupling reactions of aryl bromides and arylsiloxanes in water catalyzed by palladium complexes of phosphanes modified with crown ethers

被引：59

作者：

Gordillo, Alvaro ^{[1
]}

de Jesus, Ernesto

Lopez-Mardomingo, Carmen

机构：

[1] Univ Alcala de Henares, Dept Quim Organ, E-28871 Alcala De Henares, Madrid, Spain

[2] Univ Alcala de Henares, Dept Quim Inorgan, E-28871 Alcala De Henares, Madrid, Spain

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 16期

关键词：

D O I：

10.1021/ol061221y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The complexes [PdCl2L2], where L is a crown-ether-containing triarylphosphane, catalyze the formation of biaryls from arylsiloxanes and aryl bromides with high yields in water as solvent and under air. The water-insoluble catalysts [PdCl2(PhCN)(2)] and [PdCl2(PPh3)(2)] are also efficient, although they decompose more quickly to form black Pd-0.

引用

页码：3517 / 3520

页数：4

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