Charge Transport Orthogonality in All-Polymer Blend Transistors, Diodes, and Solar Cells

被引:61
作者
Fabiano, Simone [1 ]
Himmelberger, Scott [2 ]
Drees, Martin [3 ]
Chen, Zhihua [3 ]
Altamimi, Rashid M. [4 ]
Salleo, Alberto [2 ]
Loi, Maria Antonietta [1 ]
Facchetti, Antonio [3 ]
机构
[1] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[2] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[3] Polyera Corp, Skokie, IL 60077 USA
[4] King Abdulaziz City Sci & Technol, Petrochem Res Inst, Riyadh 11442, Saudi Arabia
基金
美国国家科学基金会;
关键词
all-polymer blends; charge transport; field-effect transistors; hierarchical structures; organic solar cells; FIELD-EFFECT TRANSISTORS; THIN-FILMS; POLY(3-HEXYLTHIOPHENE); AMBIPOLAR; PERFORMANCE; COPOLYMER; CRYSTALLIZATION; AGGREGATION; SEPARATION; TEXTURE;
D O I
10.1002/aenm.201301409
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polymer aggregation and phase separation of polymer-polymer blends are effectively tuned from self-stratified to laterally phase-separated by adjusting the relative solubility of the two polymers in the mixture. This is found to dramatically alter the charge transport characteristics from a preferential in-plane to an out-of-plane direction, revealing the critical dependence of the resulting device performance on the film morphology and structure of the active layer. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页数:7
相关论文
共 55 条
[1]   Electrical and optical simulations of a polymer-based phosphorescent organic light-emitting diode with high efficiency [J].
Al-Sa'di, Mahmoud ;
Jaiser, Frank ;
Bagnich, Sergey ;
Unger, Thomas ;
Blakesley, James ;
Wilke, Andreas ;
Neher, Dieter .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2012, 50 (22) :1567-1576
[2]   Fluorinated Copolymer PCPDTBT with Enhanced Open-Circuit Voltage and Reduced Recombination for Highly Efficient Polymer Solar Cells [J].
Albrecht, Steve ;
Janietz, Silvia ;
Schindler, Wolfram ;
Frisch, Johannes ;
Kurpiers, Jona ;
Kniepert, Juliane ;
Inal, Sahika ;
Pingel, Patrick ;
Fostiropoulos, Konstantinos ;
Koch, Norbert ;
Neher, Dieter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :14932-14944
[3]   Vertically segregated polymer-blend photovoltaic thin-film structures through surface-mediated solution processing [J].
Arias, AC ;
Corcoran, N ;
Banach, M ;
Friend, RH ;
MacKenzie, JD ;
Huck, WTS .
APPLIED PHYSICS LETTERS, 2002, 80 (10) :1695-1697
[4]   Surface-induced self-encapsulation of polymer thin-film transistors [J].
Arias, Ana Claudia ;
Endicott, Fred ;
Street, Robert A. .
ADVANCED MATERIALS, 2006, 18 (21) :2900-+
[5]   Materials and Applications for Large Area Electronics: Solution-Based Approaches [J].
Arias, Ana Claudia ;
MacKenzie, J. Devin ;
McCulloch, Iain ;
Rivnay, Jonathan ;
Salleo, Alberto .
CHEMICAL REVIEWS, 2010, 110 (01) :3-24
[6]   Nonequilibrium Polymer Rheology in Spin-Cast Films [J].
Barbero, David R. ;
Steiner, Ullrich .
PHYSICAL REVIEW LETTERS, 2009, 102 (24)
[7]   Influence of blend microstructure on bulk heterojunction organic photovoltaic performance [J].
Brabec, Christoph J. ;
Heeney, Martin ;
McCulloch, Iain ;
Nelson, Jenny .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1185-1199
[8]  
Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[9]  
2-A
[10]   High-Performance Ambipolar Diketopyrrolopyrrole-Thieno[3,2-b]thiophene Copolymer Field-Effect Transistors with Balanced Hole and Electron Mobilities [J].
Chen, Zhuoying ;
Lee, Mi Jung ;
Ashraf, Raja Shahid ;
Gu, Yun ;
Albert-Seifried, Sebastian ;
Nielsen, Martin Meedom ;
Schroeder, Bob ;
Anthopoulos, Thomas D. ;
Heeney, Martin ;
McCulloch, Iain ;
Sirringhaus, Henning .
ADVANCED MATERIALS, 2012, 24 (05) :647-+