NMR spectroscopy with spectral editing for the analysis of complex mixtures

被引:27
作者
Dixon, AM [1 ]
Larive, CK [1 ]
机构
[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA
关键词
D O I
10.1366/0003702991945704
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The nuclear magnetic resonance (NMR) methods for spectral simplication, which can be used in the analysis of complex mixtures, are summarized. These methods can be employed to gain information about the structural components of a mixture, to resolve the components of a mixture, and to characterize binding interactions that take place in solutions of mixtures. Furthermore, 3D NMR experiments and heteronuclear spin filters can be used to simplify spectra of mixtures to accurately measure diffusion coefficients of individual components. All these methods are based on basic NMR phenomena. The innovative application of the commonly-used experimental methods allows the analyst to solve complicated problems in a timely manner.
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收藏
页码:426A / 440A
页数:15
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