Cu(II)-catalyzed selective aerobic oxidation of alcohols under mild conditions

被引：163

作者：

Jiang, Nan ^{[1
]}

Ragauskas, Arthur J. ^{[1
]}

机构：

[1] Georgia Inst Technol, Dept Chem, Atlanta, GA 30332 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 18期

关键词：

D O I：

10.1021/jo060837y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient four-component system consisting of acetamido-TEMPO/Cu(ClO4)(2)/TMDP/DABCO in DMSO has been developed for room-temperature aerobic alcohol oxidation. Under the optimal conditions, various alcohols could be converted into their corresponding aldehydes or ketones in good to excellent yields. The newly developed catalytic system could also be recycled and reused for three runs without any significant loss of catalytic activity.

引用

页码：7087 / 7090

页数：4

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