Diffusion-Controlled, Self-Organized Growth of Symmetric Wrinkling Patterns

被引:179
作者
Chung, Jun Young [1 ]
Nolte, Adam J. [1 ]
Stafford, Christopher M. [1 ]
机构
[1] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA
关键词
THIN-FILMS; ELASTOMERIC POLYMER; ORDERED STRUCTURES; SURFACE; MECHANICS; SOLVENT; SKINS;
D O I
10.1002/adma.200803209
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Symmetric instability patterns in the UV-ozone crosslinked surface of a polystyrene film grow radially outward from local defect sites in the presence of solvent vapor. The diffusion kinetics of the solvent governs the pattern morphology by establishing stress fields that favor the orientation of wrinkles in a dendritic-like spoke pattern (left) or in a target pattern consisting of concentric rings (right).
引用
收藏
页码:1358 / 1362
页数:5
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