Catalytic chain transfer polymerization: an overview

被引：94

作者：

Heuts, JPA ^{[1
]}

Roberts, GE ^{[1
]}

Biasutti, JD ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 6-7期

关键词：

D O I：

10.1071/CH02098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic chain transfer polymerization is a very efficient and versatile free-radical polymerization technique for the synthesis of functional macromonomers. The process is based on the ability of certain transition metal complexes, most notably of low-spin Co-II complexes such as cobaloximes, to catalyse the chain transfer to monomer reaction. A brief overview is given of the applications and the mechanistic understanding of catalytic chain transfer polymerization.

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页码：381 / 398

页数：18

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